國立嘉義大學

梁孟 教授

一、學歷：

美國堪薩斯州立大學化學系博士

國立凊華大學化工系博士後研究

中國技術服務社觸媒研究中心副研究師

長春人造樹脂有限公司新竹廠研發部 課長

嘉義大學應用化學系暨研究所助理教授,副教授,教授

四、連絡方式（ Tel or e-mail)：

  052717952

   mliang@mail.ncyu.edu.tw

五、研究方向：

 Our research emphasizes on theme of synthetic macromolecular in organic and inorganic chemistry. In particular, we are interested in the design and synthesis of telechelic macromolecules and oligomers that could undergo thermal curing reactions to afford new polymer materials with improved thermal 、 electrical and flammability properties; or they could be used as a block polymer precursor for new material developments. The research goal is aimed to meet the never-end requests of faster transportation speed 、 higher circuit density and lighter weight of electronic devices for next generation products. Currently, two new types of telechelic polymers have been successfully developed in our laboratory and the reactivity 、 polymerization behavior 、 structure/property relationship correlation and physical 、 chemical properties of the curing products are under investigations. It is anticipated that this research will provide valuable insight into the relationship between polymerization behavior and structure in thermosetting systems and would provide students with a broad training in synthesis and characterization techniques in organic, inorganic and polymer chemistry.

六、期刊著作：

1. Lu, C. H.;  Chang, C.;  Huang, Y. C. ;  You, J. X.;  Liang, M.* Synthesis and Characterization of DOPO-Containing Poly(2,6-dimethyl-1,4-phenylene oxide)s by Oxidative Coupling Polymerization. Polymers. 2024, 16(2), 303-338.
   
2. Ye, J. Y.; Peng, K. F.; Zhang, Y. N.; Huang, S. Y.; Liang, M.* Synthesis and Characterization of N-Substituted Polyether-Block-Amide Copolymers. Materials. 2021, 14, 773.
3. Wang, Y. M.; Zheng, S. X.; Chang, H. I.; H.Y. Tsai, H. Y.; Liang, M.* Microwave-Assisted Synthesis of Thermo- and pH-responsive Antitumor Drug Carrier Through Reversible Addition－Fragmentation Chain Transfer Polymerization. Express Polym. Lett. 2017, 11, 293-307.
4. Han, Y. J.; Lin, C. Y.; Liang, M.*; Liu, Y. L. Radical and Atom Transfer Halogenation (RATH): A Facile Route for Chemical and Polymer Functionalization. Macromol. Rapid. Commun. 2016, 37, 845-850.
5. Visakh, P. M.; Liang, M.* Eds. Poly(Ethylene Terephthalate) Based Blends, Composites and Nanocomposites. Elsevier & William Andrew Applied Science Publishers, ISBN:9780323313063, 2015.
6. Liang, M.*; Yang, T. M.; Chang, H. P.; Wang, Y. M. Dual-Responsive Polymer-Drug Nanoparticles for Drug Delivery. Reac. Func. Polym. 2015, 86, 27-36.
7. Shiau, S. F.; Juang, T. Y.; Chou, H. W.; Liang, M.* Synthesis and Properties of New Water-Soluble Aliphatic Hyperbranched Poly(amino acids) with High pH-Dependence Photoluminescene. Polymer, 2013, 44, 623-630.
8. Lin, Y. C.; Feng, H. C.; Yang, M. S.; Yu, H. A.; Huang, C. C.; Liang, M.* Synthesis, Characterization and Thermal Properties of Functionalized Poly(2.6-dimethyl-1,4 phenylene oxide)s Containing Ethylenic, Aldehydric, Hydroxyl and Acrylate Pendant Groups. Polym. Int. 2012, 61, 719-726.
9. Chang, H. P.; Chen, J. Y.; Zhong, P. S.; Chang, Y. H.; Liang, M.* Synthesis, Characterization of a New Polymer-Drug Conjugate with pH-Induced Activity. Polymer. 2012, 53, 3498-3507.
10. Liang, M.* (2011) “Polyphenylene Oxide” Chap 2 in: Handbook of Engineering and Specialty Thermoplastics, Vol. 3: Polyethers and Polyesters. 15-53. Sabu, T.; Visakh, P.M., Eds. John Wiley & Scrivener Publishing, ISBN: 9780470639269, Pub Date:06/15/2011 (Invited Chapter).
11. Chang, H. I.; Yang, M. S.; Liang, M.* The Synthesis, Characterization and Antibacterial Activity of Quaternized Poly(2.6-dimethyl-1,4 phenylene oxide)s Modified with Ammonium and Phosphonium Salts. Reac. Func. Polym. 2010, 70, 944-950.
12. Su, C. T.; Lin, K. U.; Lee, T. J.; Liang, M.* Preparation, Characterization and Curing Properties of Epoxy-terminated Poly(2.6-dimethyl-1,4 phenylene oxide)s. Eur. Polym. J.  2010, 46, 1488-1497.
13. Liang, M.*; Jhuang, Y. J.; Zhang, C. F.; Tsai, W. J.; Feng, H. C. Synthesis and Characterization of Poly(phenylene oxide) Graft Copolymers by Atom Transfer Radical Polymerizations. Eur. Polym. J. 2009, 45, 2348-2357.
14. Lin, K. Y.; Su, C. T.; Wang, L. J.; Huang, C. L.; Liang, M.* New Manganese Catalyzed Regiocontrolled Synthesis of Poly(2,5-dialkyl-1,4-phenylene oxide)s. J. Appl. Polym. Sci. 2009, 111, 1501-1507.
15. Liu , Y. L.; Chang Y. H.; Liang, M. Poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) Multi-bonded Carbon Nanotube (CNT): Preparation and Formation of PPO/CNT Nanocomposites. Polymer. 2008, 49, 5405–5409.
16. Lee, T. J.; Fang, Y. D.; Yuan, W. G.; Wei, K. M.; Liang, M.* Synthesis, Structures and Thermal Properties of New Class Epoxide-terminated Telechelic Poly(2,6-dimethyl- 1,4-phenylene oxide)s.  Polymer. 2007, 48, 734-742.
17. Huang, C.C.; Yang, M. S. ; Liang, M.* Synthesis of New Thermosetting Poly(2,6-dimethyl-1,4-phenylene oxide) Containing Epoxide Pendant Groups. J. Polym. Sci. Part A: Polym. Chem. 2006, 44, 5875-5886.
18. Gates, D; Park, P.; Liang, M.*; Edwards, M.; Angelakos, C.; Liable-Sands, L.; Rheingold, A.; Manners, I. Regioselective Substitution Reactions of Sulfur(VI)-Nitrogen-Ohosphorus Rings: Reactions of the Halogenated Cyclic Thionylphosphazenes[NSOX(NPCl 2 ) 2 ] (X=Cl or F) with Oxygen-Based Nucleophiles. Inorg. Chem. 1996, 35, 4301-4309.
19. Ni, Y; Stammer, A.; Liang, M.*; Massey, J.; Vansco, G. J.; Manners, I. Polymers with Sulfur(VI)-Nitrogen-Phosphorus Backbones: Synthesis, Characterization, and Properties of Atactic Poly[(amino)thionylphosphazenes]. Macromolecules.1996, 29, 3401-3408.
20. Liang, M.*; Lee, C.C.; Chen , S.A. A New Method of Preparing Poly(benzo [ c ] thiophene) Composite Films with Poly(methyl methacrylate). Makromol. Chem., Rapid Commun. 1993, 14, 761-764.
21. Rogers, R. D.; Macomber, D. W.; Liang, M.* Crystal Structure of A( m -Bis(carbene)) Dimetal Complex of Tungsten. J. Crystallogr. Spectro. Res. 1993, 23(8), 623-628.
22. Ni, Y; Stammer, A.; Liang, M.*; Massey, J.; Vansco, G.J.; Manners, I. Synthesis, Glass Transition Behavior and Solution Characterization of Poly [ (aroxy)thionylphosphazenes ] with Halogen Substituents at Sulfur. Macromolecules. 1992, 25, 7119-7125.
23. Liang, M.*; Waddling, C.; Honeyman, C.; Foucher, D.; Manners I. Ring-Opening Polymerization as A Route to New Inorganic Macromolecules. Phosphorus, Sulfur, and Silicon and Related Elements. 1992, 64, 113-120.
24. Liang, M.*; Foucher, D.; Manners, I. Inorganic Rings as Precursors to Inorganic Polymers and Macrocycles. Polymers Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1992, 33(1), 1134.
25. Maatta, E. A.; Liang, M.* Coupling High-Valent Metals with p-donor Ligands: Ortho- and Paraphenylenediimido Ditungsten Complexes. Inorg. Chem. 1992, 31, 953-956.
    
26. Liang, M.*; Manners, I. Poly(thionylphosphazenes): A New Class of Inorganic Polymers with Skeletal Phosphorus, Nitrogen, and Sulfur (VI) Atoms.  J. Am. Chem. Soc. 1991, 113, 4044-4545. See also Chem. Eng. News, 1991, 69(19), 24.
27. Liang, M.*; Waddling, C, Manners, I. Poly(thinoylphosphazenes): A New class of Inorganic Polymers with Backbones of Phosphorus, Nitrogen, and Sulfur (VI) Atoms. Polymer Prepr. (Am. Chem. Soc. Div. Polym. Chem.) 1991, 32(2), 487.
28. Liang, M.*; Manners, I. Poly(thionylphosphazenes) with Fluorine Substituents at Sulfur: A New Class of Inorganic Fluoropolymers. Makromol. Chem. Rapid Comm. 1991, 12, 613.
29. Macomber, D. W.; Hung, M. H.; Madhukar, P.; Liang, M.; Rogers, R. D. Synthesis and Structures of ( m -Bis(carbene)) Dimetallic Complexes of Chromium and Tungsten. Organometallics, 1991, 10, 737.
30. Macomber, D. W.; Liang, M.; Madhukar P.; Verma, A.G. Synthesis and Reactivity of the a , b -Unsaturated Tungsten Carbene Complexes (CO)5W [ C(OC 3)CH=CH2]. J. Organomet. Chem. 1989, 361, 187.
31. Macomber, D. W.; Liang, M.; Rogers , R. D. Synthesis and Reactivity of Di-tungsten m -Carbene Complexes: X-Ray Crystal Structure of W2(CO)9[ m -h1 , h3 C(OCH3 )C=CH(CH2)5CH2 ]. Organometallics, 1988, 7, 416.
32. Macomber, D. W.; Hung, M. H.; Liang, M.; Verma, A. G.;Madhukar, P. New Organometallic Polymers Containing Tungsten Carbene Complexes. Macromolecules, 1988, 21, 1187.

七、 研討會論文

 八、研究計畫：

九、其他：

專利

1. 熱應答型高分子聚合物及其製備方法與應用(Thermoresponsive copolymer preparation and application thereof). 中華民國專利,發明第 I 431017號, 2014.3.21.
2. 不含鹵素的樹脂組成物 (A Non-halogenate resin compositions for laminate). 日本專利，公告第3729821號。2005.10.14.
3. 二 ( 烷氧羰胺基芳基 ) 甲烷類之製法 (A Process for Producing Di (alkoxylcarbonyl -aminoaryl)Methane). 中華民國專利，公告號 :00419451 ，發明第 126905 號， 2001.1.21
4. 4,4- 二苯基甲烷二胺基甲酸酯之製備方法 (A Non-phosgene route to 4,4 ' -methylene diphenylene urethane ). 中華民國專利，公告號 :00299312 ，發明第 085003 號， 1997.3.1. 。
5. 非光氣法胺基甲酸酯之製備方法 (A Non-phosgene route to methylphenylcarbamate). 中華民國專利，公告號 :00255882 ，發明第 073456 號， 1995.9.1.
6. Poly(thionylphosphazenes). Manners, I.,Liang M., Ostrowicki, A.; USA : US 5241017 ， Europe: EP 0504694 ， Canada :CA2063188 。

十、教授課目：

無機化學、高分子化學、高等無機、觸媒化學、複合材料、液晶材料、無機材料特論